The transition from the ground state to the first rotational excited state in diatomic oxygen (O2) requires 356 μeV. At what temperature would the thermal energy k T be sufficient to set diatomic oxygen into rotation? Would you ever find diatomic oxygen exhibiting the specific heat of a monatomic gas at normal pressure? | Numerade
The transition from the ground state to the first rotational excited state …
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SOLVED:(a) Draw diagrams to show the occupancies of the πg^* level in the ground state and first two excited states of O2 . Does the formal bond order change upon excitation from the ground to the first excited state (^1 Δg) of O2 ? (b) The ^1 Δg state of O2 lies 94.7 kJ mol^-1 above the ground state. Show that the simultaneous excitation of two O2 molecules from their ground to ^1 Δg states corresponds to an absorption of light of wavelength 631 nm
SOLVED:(a) Draw diagrams to show the occupancies of the πg^* level …
May 12, 2020
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